PHILADELPHIA â Electronic circuits are typically integrated in rigid silicon wafers, but flexibility opens up a wide range of applications. In a world where electronics are becoming more pervasive, flexibility is a highly desirable trait, but finding materials with the right mix of performance and manufacturing cost remains a challenge.
Now a team of researchers from the University of Pennsylvania has shown that nanoscale particles, or nanocrystals, of the semiconductor cadmium selenide can be "printed" or "coated" on flexible plastics to form high-performance electronics.
The research was led by David Kim, a doctoral student in the Department of Materials Science and Engineering in Pennâs School of Engineering and Applied Science; Yuming Lai, a doctoral student in the Engineering Schoolâs Department of Electrical and Systems Engineering; and professor Cherie Kagan, who has appointments in both departments as well as in the School of Arts and Sciencesâ Department of Chemistry. Benjamin Diroll, a doctoral student in chemistry, and Penn Integrates Knowledge Professor Christopher Murray of Materials Science and of Chemistry also collaborated on the research.
Their work was published in the journal Nature Communications.
âWe have a performance benchmark in amorphous silicon, which is the material that runs the display in your laptop, among other devices,â Kagan said. âHere, we show that these cadmium selenide nanocrystal devices can move electrons 22 times faster than in amorphous silicon."
Besides speed, another advantage cadmium selenide nanocrystals have over amorphous silicon is the temperature at which they are deposited. Whereas amorphous silicon uses a process that operates at several hundred degrees, cadmium selenide nanocrystals can be deposited at room temperature and annealed at mild temperatures, opening up the possibility of using more flexible plastic foundations.
Another innovation that allowed the researchers to use flexible plastic was their choice of ligands, the chemical chains that extend from the nanocrystalsâ surfaces and helps facilitate conductivity as they are packed together into a film.
âThere have been a lot of electron transport studies on cadmium selenide, but until recently we havenât been able to get good performance out of them,â Kim said. âThe new aspect of our research was that we used ligands that we can translate very easily onto the flexible plastic; other ligands are so caustic that the plastic actually melts.â
Because the nanocrystals are dispersed in an ink-like liquid, multiple types of deposition techniques can be used to make circuits. In their study, the researchers used spincoating, where centrifugal force pulls a thin layer of the solution over a surface, but the nanocrystals could be applied through dipping, spraying or ink-jet printing as well.
On a flexible plastic sheet a bottom layer of electrodes was patterned using a shadow mask â essentially a stencil â to mark off one level of the circuit. The researchers then used the stencil to define small regions of conducting gold to make the electrical connections to upper levels that would form the circuit. An insulating aluminum oxide layer was introduced and a 30-nanometer layer of nanocrystals was coated from solution. Finally, electrodes on the top level were deposited through shadow masks to ultimately form the circuits.
âThe more complex circuits are like buildings with multiple floors,â Kagan said. âThe gold acts like staircases that the electrons can use to travel between those floors.â
Using this process, the researchers built three kinds of circuits to test the nanocrystals performance for circuit applications: an inverter, an amplifier and a ring oscillator.
âAn inverter is the fundamental building block for more complex circuits,â Lai said. âWe can also show amplifiers, which amplify the signal amplitude in analog circuits, and ring oscillators, where âonâ and âoffâ signals are properly propagating over multiple stages in digital circuits.â
âAnd all of these circuits operate with a couple of volts,â Kagan said. âIf you want electronics for portable devices that are going to work with batteries, they have to operate at low voltage or they wonât be useful.â
With the combination of flexibility, relatively simple fabrication processes and low power requirements, these cadmium selenide nanocrystal circuits could pave the way for new kinds of devices and pervasive sensors, which could have biomedical or security applications.
âThis research also opens up the possibility of using other kinds of nanocrystals, as weâve shown the materials aspect is not a limitation any more,â Kim said.