Graphene, a material that consists of a lattice of carbon atoms, one atom thick, is widely touted as being the most electrically conductive material ever studied. However, not all graphene is the same. With so few atoms comprising the entirety of the material, the arrangement of each one has an impact on its overall function.
Now, for the first time, researchers from the University of Pennsylvania have used a cutting-edge microscope to study the relationship between the atomic geometry of a ribbon of graphene and its electrical properties.
A deeper understanding of this relationship will be necessary for the design of graphene-based integrated circuits, computer chips and other electronic devices.
The study was led by professors A.T. Charlie Johnson and Marija DrndiÄ, both of the Department of Physics and Astronomy in Pennâs School of Arts & Sciences, along with Zhengqing John Qi, a member of Johnsonâs lab, and Julio RodrĂguez-Manzo from Drndicâs lab. Sung Ju Hong, then a member of Johnsonâs lab, also contributed to the study.
Their study was published in the journal Nano Letters.
The teamâs experiments were enabled by Brookhavenâs aberration-corrected transmission electron microscope, or AC-TEM. By focusing the microscopeâs electron beam, the researchers were able to controllably cut sheets of graphene into ribbons with widths as small as 10 nanometers, while keeping them connected to an electricity source outside the microscope. They then could use the AC-TEMâs nanoscopic resolution to distinguish between individual carbon atoms within those ribbons. This level of precision was necessary to determine how the carbon atoms on the edges of the nanoribbons were oriented.
âWeâre relating the structure of the graphene â its atomic arrangement â to its electrical transport properties,â said DrndiÄ. âIn particular, we were looking at the edges, which we were able to identify the geometry of.â
âGraphene looks like chicken wire, and you can cut up this hexagonal lattice of carbon atoms in different ways, producing different shapes on the edge,â she said. âBut if you cut it one way, it might behave more like a metal, and, if you cut it another way, it could be more like a semiconductor.â
For any piece of graphene, either the pointy or flat sides of its carbon hexagons might be at the pieceâs edge. Where the pointy sides face outward, the edge has a âzig-zagâ pattern. Flat sides produce âarmchairâ pattern when they are on an edge. Any given edge might also display a mix of the two, depending on how the piece of graphene was initially cut and how that edge degrades under stress.
Because the graphene nanoribbons were connected to an electricity source while they were inside the AC-TEM, the researchers were able to simultaneously trace the outline of the ribbons and measure their conductivity. This allowed the two figures to be correlated.
âIf you want to use graphene nanoribbons in computer chips, for example, you absolutely need to have this information,â Johnson said. âPeople have looked at these ribbons under the microscope, and people have measured their electrical properties without looking at them but never both at the same time.â
After studying the nanoribbons with relatively low levels of electron flow, the researchers turned up the intensity, much like turning up a light bulb using a dimmer switch The combination of the electron bombardment from the microscope and the large amount of electrons flowing through the nanoribbons caused their structures to gradually degrade. As carbon bonds within the nanoribbons broke, they became thinner and the shape of their edges changed, providing additional data points.
âBy doing everything within the microscope,â RodrĂguez-Manzo said, âwe can just follow this transformation to the end, measuring currents for the nanoribbons even when the get smaller than 1 nanometer across. Thatâs five atoms wide.â
This kind of stress testing is critical to the future design of graphene electronics.
âWe have to see how much current we can transport before these nanoribbons fall apart. Our data shows that this figure is high compared to copper,â RodrĂguez-Manzo said.
The harsh conditions also caused some of the ribbons to fold up on themselves, producing nanoscopic graphene loops. Serendipitously, the team found that these loops had desirable properties.
âWhen the edges wrap around and form the loops we see,â Johnson said, âit helps hold the structure together, and it makes the current density a thousand higher than what is currently state of the art. That structure would be useful in making interconnects, which are the conducting paths that connect transistors together in integrated circuits.â
Future research in this field will involve directly comparing the electrical properties of graphene nanoribbons with different widths and edge shapes.
âOnce we can cut these nanoribbons atom by atom,â DrndiÄ said, âthere will be a lot more we can achieve.â
The research was supported by the National Science Foundation, the National Institutes of Health, the U.S. Department of Energy, Belgiumâs Fonds de la Recherche Scientifique, South Koreaâs Ministry of Education, Science and Technology and National Research Foundation and the European Unionâs Graphene Flagship Consortium.
AndrĂ©s R. Botello-MĂ©ndez and Jean-Christophe Charlier of the UniversitĂ© Catholique de Louvain in Belgium, Eric Stach of Brookhaven National Laboratory and Yung Woo Park of Seoul National University also contributed to the study.